Publicación: Eco-friendly catalytic systems based on MgO- Supporting carbon materials for the Friedländer condensation
Cargando...
Fecha
2014-12
Editor/a
Director/a
Tutor/a
Coordinador/a
Prologuista
Revisor/a
Ilustrador/a
Derechos de acceso
info:eu-repo/semantics/openAccess
Título de la revista
ISSN de la revista
Título del volumen
Editor
Wiley
Resumen
Carbon-supported MgO materials are excellent and sustainable catalysts for the synthesis of N-containing heterocyclic compounds by the Friedländer condensation under mild, solvent-free conditions. The results reported herein indicate that MgO is the most active catalytic species that accelerates the reaction compared with the catalytic behavior observed for the carbon material Norit RX3. On the basis of DFT calculations, a reaction mechanism that involves dual activation of the reacting structures by the catalyst is proposed. Oxide, outside: MgO supported on carbon is able to catalyze the synthesis of interesting N-containing heterocyclic compounds efficiently under mild conditions. MgO on the carbon surface is responsible for the catalytic behavior. These carbon materials are environmentally friendly catalysts for the Friedländer reaction.
Descripción
Esta es la versión aceptada del artículo. La versión registrada fue publicada por primera vez en ChemCatChemVolume 6, Issue 12, Pages 3440 - 3447, está disponible en línea en el sitio web del editor:
https://doi.org/10.1002/cctc.201402602.
This is the accepted version of the article. The registered version was first published in ChemCatChemVolume 6, Issue 12, Pages 3440 - 3447, it is available online on the publisher's website:
https://doi.org/10.1002/cctc.201402602.
Categorías UNESCO
Palabras clave
carbon, magnesium, nitrogen heterocycles, reaction mechanisms, supported catalysts
Citación
M. Godino-Ojer, A. J. López- Peinado, R. M. Martín-Aranda, J. Przepiórski, E. Pérez-Mayoral, and E. Soriano (2014) Eco-friendly Catalytic Systems Based on MgO- Supporting Carbon Materials for the Friedländer Condensation ChemCatChemVolume 6, Issue 12, Pages 3440 - 344, https://doi.org/10.1002/cctc.201402602
Centro
Facultad de Ciencias
Departamento
Química Inorgánica y Química Técnica