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Publicación
Self-Standing Nanofiber Electrodes with Pt–Co Derived from Electrospun Zeolitic Imidazolate Framework for High Temperature PEM Fuel Cells
(Wiley, 2021) Lim, Sung Yul; Martín Fernández, Santiago; Gao, Guohua; Dou, Yibo; Bredmose Simonsen, Søren; Jensen, Jens Oluf; Li, Qingfeng; Norrman, Kion; Jing, Shao; Zhang, Wenjing; https://orcid.org/0000-0002-5011-1951
Expedited conversion of O2 to H2O with minimal amounts of Pt is essential for wide applicability of PEM fuel cells (PEMFCs). Therefore, it is imperative to develop a process for catalyst management to circumvent unnecessary catalyst loss while improving the Pt utilization, catalytic activity, and durability. Here, the fabrication of a self-standing nanofiber electrode is demonstrated by employing electrospinning. This film-type catalyst simultaneously contains Pt–Co alloy nanoparticles and Co embedded in an N-doped graphitized carbon (Co–Nx) support derived from the electrospun zeolitic imidazolate frameworks. Notably, the flexible electrode is directly transferrable for the membrane-electrode assembly of high temperature PEMFC. In addition, the electrodes exhibit excellent performance, maybe owing to the synergistic interaction between the Pt–Co and Co–Nx as revealed by the computational modeling study. This method simplifies the fabrication and operation of cell device with negligible Pt loss, compared to ink-based conventional catalyst coating methods.
Publicación
Polybenzimidazole-Based High-Temperature Polymer Electrolyte Membrane Fuel Cells: New Insights and Recent Progress
(Springer, 2020) Aili, David; Henkensmeier, Dirk; Martín Fernández, Santiago; Singh, Bhupendra; Hu, Yang; Jensen, Jens Oluf; Cleemann, Lars Nilausen; Li, Qingfeng; https://orcid.org/0000-0002-3510-135X; https://orcid.org/0000-0003-2330-953X; https://orcid.org/0000-0002-0773-5312; https://orcid.org/0000-0001-8644-9615; https://orcid.org/0000-0002-2427-7763; https://orcid.org/0000-0001-5840-7477; https://orcid.org/0000-0002-5460-055X
High-temperature proton exchange membrane fuel cells based on phosphoric acid-doped polybenzimidazole membranes are a technology characterized by simplified construction and operation along with possible integration with, e.g., methanol reformers. Significant progress has been achieved in terms of key materials, components and systems. This review is devoted to updating new insights into the fundamental understanding and technological deployment of this technology. Polymers are synthetically modified with basic functionalities, and membranes are improved through cross-linking and inorganic–organic hybridization. New insights into phosphoric acid along with its interactions with basic polymers, metal catalysts and carbon-based supports are recapped. Recognition of parasitic acid migration raises acid retention issues at high current densities. Acid loss via evaporation is estimated with respect to the acid inventory of membrane electrode assembly. Acid adsorption on platinum surfaces can be alleviated for platinum alloys and non-precious metal catalysts. Binders have been considered a key to the establishment of the triple-phase boundary, while recent development of binderless electrodes opens new avenues toward low Pt loadings. Often ignored microporous layers and water impacts are also discussed. Of special concern are durability issues including acid loss, platinum sintering and carbon corrosion, the latter being critical during start/stop cycling with mitigation measures proposed. Long-term durability has been demonstrated with a voltage degradation rate of less than 1 μV h−1 under steady-state tests at 160 °C, while challenges remain at higher temperatures, current densities or reactant stoichiometries, particularly during dynamic operation with thermal, load or start/stop cycling.
Publicación
Protic ionic liquids immobilized in phosphoric acid-doped polybenzimidazole matrix enable polymer electrolyte fuel cell operation at 200 °C
(ELSEVIER, 2020) Skorikova, Galina S.; Rauber, Daniel; Aili, David; Martín Fernández, Santiago; Li, Qingfeng; Henkensmeier, Dirk; Hempelmann, Rolf; https://orcid.org/0000-0003-0488-4344; https://orcid.org/0000-0002-3510-135X; https://orcid.org/0000-0002-5460-055X; https://orcid.org/0000-0003-2330-953X
Protic ionic liquids (PILs) based on the anion bis(trifluoromethanesulfonyl)imide were confined in polybenzimidazole (PBI) matrices. Quasi-solidified ionic liquid membranes (QSILMs) were fabricated and examined for mechanical and thermal stability. After doping in phosphoric acid (PA), the QSILMs exhibited conductivities of 30–60 mS cm−1 at 180 °C. Fluorescence microscopy was used to investigate the structure of the composite PBI membranes. Membrane-electrode assemblies, fabricated with PA doped QSILMs, were tested in a single fuel cell and exhibited a performance increase with increasing temperature up to 200 °C. The best performance was obtained for the membrane electrode assembly containing 50 mol% of diethyl-methyl-ammonium bis(trifluoromethylsulfonyl)imide confined in the phosphoric acid doped PBI matrix with closed porosity. It reached 0.32 W cm−2 at 200 °C and 900 mA cm−2 . The catalyst layer of the gas diffusion electrode impregnated with protic ionic liquid exhibited better long-term stability than the gas diffusion electrode impregnated with phosphoric acid within 100 h of operation at 200 °C and anhydrous conditions.