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Enhancement of a Simple, Economic and Eco-Friendly Analytical Approach for the Extraction and Determination of Endocrine Disruptors from Plastics in Shrimp

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dc.contributor.authorSoliz Rojas, Dulce Lucy
dc.contributor.authorGarcía González, Jorge
dc.contributor.authorPaniagua González, Gema
dc.contributor.authorGarcinuño Martínez, Rosa Mª
dc.contributor.authorBravo Yagüe, Juan Carlos
dc.contributor.authorFernández Hernando, Pilar
dc.date.accessioned2024-07-31T12:13:59Z
dc.date.available2024-07-31T12:13:59Z
dc.date.issued2024-07-12
dc.description.abstractThe economic significance of the shrimp industry relies heavily on the comprehensive utilization of all of the shrimp’s parts. However, this importance is often threatened by common challenges such as disease and pollution, caused by prominent contaminants that are capable of exerting adverse effects either directly as physical pollutants or indirectly through the incorporation of additives or adsorbed chemicals. Among these substances are endocrine disruptors, which pose risks to both wildlife and human populations. In this study, 11 endocrine-disrupting compounds were determined (3 bisphenols, 3 phthalates, 3 pesticides, and 2 nonylphenols) through the development of a cost-effective, greener and cost-friendly method based on solid-phase matrix dispersion (MSPD) with high-performance liquid chromatography coupled with diode array detection (HPLC-DAD). Determinations were performed on different parts of the shrimp: the cephalothorax, abdomen, intestine and shell. Several variables were optimized in the extraction, separation and detection phases, resulting in average recoveries of about 90%. The limit of detection (LOD) varies depending on the analyte and matrix. At concentrations of 1 mg/kg in the cephalothorax+shells and 1.25 mg/kg in the abdomen+intestine, all compounds were detected, except for nonylphenols. The developed method has allowed the simultaneous determination of 11 endocrine disruptors in different parts of the shrimp samples. Furthermore, the MSPD has been demonstrated to be an efficacious, selective, and streamlined sample extraction method, eliminating the necessity for pretreatment steps such as centrifugation and filtration, as well as the use of large volumes of solvents.en
dc.description.versionversión publicada
dc.identifier.citationSoliz, D.L.; García-González, J.; Paniagua González, G.; Garcinuño, R.M.; Bravo Yagüe, J.C.; Fernández Hernando, P. Enhancement of a Simple, Economic and Eco-Friendly Analytical Approach for the Extraction and Determination of Endocrine Disruptors from Plastics in Shrimp. Sustainability 2024, 16, 5978. https://doi.org/10.3390/su16145978
dc.identifier.doihttps://doi.org/10.3390/su16145978
dc.identifier.issn2071-1050
dc.identifier.urihttps://hdl.handle.net/20.500.14468/23172
dc.journal.titleSustainability
dc.journal.volume16
dc.language.isoen
dc.publisherMDPI
dc.relation.centerFacultad de Ciencias
dc.relation.departmentCiencias Analíticas
dc.rightsinfo:eu-repo/semantics/openAccess
dc.rights.licenseAtribución-NoComercial-SinDerivadas 4.0 Internacional
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/deed.es
dc.subject24 Ciencias de la Vida
dc.subject23 Química
dc.subject.keywordsgreen chemistryen
dc.subject.keywordsbisphenolsen
dc.subject.keywordsftalatesen
dc.subject.keywordsalquilphenolsen
dc.subject.keywordsnonylphenolsen
dc.subject.keywordsorganochlorine pesticidesen
dc.subject.keywordsshrimpsen
dc.subject.keywordsMSPDen
dc.subject.keywordsHPLC-DADen
dc.titleEnhancement of a Simple, Economic and Eco-Friendly Analytical Approach for the Extraction and Determination of Endocrine Disruptors from Plastics in Shrimpen
dc.typeartículoes
dc.typejournal articleen
dspace.entity.typePublication
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relation.isAuthorOfPublication.latestForDiscovery974ea57f-88a0-4bea-930f-76a42ff78c76
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