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Fatty alcohol/water reaction-separation platform to produce propylene carbonate from captured CO2 using a hydrophobic ionic liquid

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dc.contributor.authorHernández, Elisa
dc.contributor.authorMoya, Cristian
dc.contributor.authorVela, Sonia
dc.contributor.authorNavarro, Pablo
dc.contributor.authorPalomar Herrero, José Francisco
dc.contributor.authorSantiago Lorenzo, Rubén
dc.date.accessioned2024-05-20T11:39:56Z
dc.date.available2024-05-20T11:39:56Z
dc.date.issued2021-11-15
dc.description.abstractThe combined use of a hydrophobic ionic liquid catalyst and a fatty alcohol is presented to synergistically improve cycloaddition reaction of CO2 to epoxides producing cyclic carbonates and envision catalyst recovery by cyclic carbonate removal using water as extracting solvent. This approach is described for the production of propylene carbonate using trihexyl(tetradecyl)phosphonium 2-cyanopyrrolide catalyst -which chemically captures CO2 reactant- and 1-decanol/water mixture as extracting solvent. The novel use of fatty alcohols on CO2 cycloaddition reaction not only permits the effective separation of the catalyst and the product purification, but also improves the CO2 conversion in the reactor, and opens the challenge of process intensification by integrated CO2 capture and conversion.en
dc.description.versionversión final
dc.identifier.doi10.1016/j.seppur.2021.119143
dc.identifier.issn1873-3794
dc.identifier.urihttps://hdl.handle.net/20.500.14468/12387
dc.journal.titleSeparation and Purification Technology
dc.journal.volume275
dc.publisherElsevier
dc.relation.centerE.T.S. de Ingenieros Industriales
dc.relation.departmentIngeniería Eléctrica, Electrónica, Control, Telemática y Química Aplicada a la Ingeniería
dc.rightsAtribución-NoComercial-SinDerivadas 4.0 Internacional
dc.rightsinfo:eu-repo/semantics/openAccess
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0
dc.subject.keywordsCO2 conversion
dc.subject.keywordsIonic liquids
dc.subject.keywordsCyclic carbonates
dc.subject.keywordsFatty alcohols
dc.subject.keywordsWater
dc.titleFatty alcohol/water reaction-separation platform to produce propylene carbonate from captured CO2 using a hydrophobic ionic liquides
dc.typeartículoes
dc.typejournal articleen
dspace.entity.typePublication
relation.isAuthorOfPublicationbfdcfb75-60b5-42a3-969d-538d9c6f42bc
relation.isAuthorOfPublication.latestForDiscoverybfdcfb75-60b5-42a3-969d-538d9c6f42bc
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