Publicación: Basolites: A type of Metal Organic Frameworks highly efficient in the one-pot synthesis of quinoxalines from α-hydroxy ketones under aerobic conditions
Fecha
2020-04-01
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Derechos de acceso
info:eu-repo/semantics/openAccess
Título de la revista
ISSN de la revista
Título del volumen
Editor
Elsevier
Resumen
We report here efficient synthesis of quinoxalines from o-phenylendiamine and α-hydroxy ketones over commercial Basolites. The concentration and type of acid centres, as CUS sites, together with the porosity of the samples strongly influence the resulting conversion and selectivity. Our results indicate that the formation of quinoxalines preferentially follows a new route, in which tautomerization reactions are also involved.
Descripción
Esta es la versión aceptada del artículo. La versión registrada fue publicada por primera vez en Catalysis Today, Volume 345, 2020, Pages 258-266, está disponible en línea en el sitio web del editor:
https://doi.org/10.1016/j.cattod.2019.08.002.
This is the accepted version of the article. The recorded version was first published in Catalysis Today, Volume 345, 2020, Pages 258-266, is available online on the publisher's website:
https://doi.org/10.1016/j.cattod.2019.08.002.
Categorías UNESCO
Palabras clave
Basolites, metal-organic-frameworks, nanocatalysts, fine chemicals, quinoxalines
Citación
Marina Godino-Ojer, Mariya Shamzhy, Jiři Čejka, Elena Pérez-Mayoral, Basolites: A type of Metal Organic Frameworks highly efficient in the one-pot synthesis of quinoxalines from α-hydroxy ketones under aerobic conditions, Catalysis Today, Volume 345, 2020, Pages 258-266, ISSN 0920-5861, https://doi.org/10.1016/j.cattod.2019.08.002.
Centro
Facultades y escuelas::Facultad de Ciencias
Departamento
Química Inorgánica y Química Técnica