Persona: Rubio Álvarez, Miguel Ángel
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0000-0002-4210-0443
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Rubio Álvarez
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Miguel Ángel
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Publicación Linear shear rheology of aging β-casein films adsorbing at the air/water interface(Elsevier, 2018-02-01) Martínez Pedrero, F.; Sánchez Puga, Pablo; Chulia Jordan, R.; González Rubio, Ramón; Tajuelo Rodríguez, Javier; Ortega Coloma, Francisco Javier; Rubio Álvarez, Miguel ÁngelIn this work, the viscoelasticity of fragile β-casein films has been followed using different macro- and microrheological techniques. The modulus of the complex surface viscosity varies with time, allowing for the monitoring of the protein adsorption and annealing. β-casein adsorption creates a soft glassy gel at the interface that experiences an aging process. Macrorheological experiments with multiple probe sizes in addition to microrheological experiments demonstrated the consistency of the surface rheological properties over a broad range of viscosities. Surface pressure measurements were performed to complement the characterization of the processes.Publicación Shear rheology of fluid interfaces: Closing the gap between macro- and micro-rheology(Elsevier, 2018-09) Guzmán Solís, Eduardo; Pastor Ruiz, Juan Manuel; González Rubio, Ramón; Tajuelo Rodríguez, Javier; Rubio Álvarez, Miguel Ángel; Ortega Coloma, Francisco JavierFor many years the determination of the shear viscosity of interfacial layers has been source of strong controversy. This is mainly because different techniques provided different values of such parameter, which leads in many cases to a puzzling interpretation of the experimental results. One possible explanation of this is the non-correct analysis of the hydrodynamic conditions of the measurement and, in particular, the assumption of some approximations that may not be necessarily valid in all cases. The introduction of hydrodynamic consideration in the study of interfacial shear rheology has helped to clarify some of the existing discrepancies between measurements performed using different devices, thus allowing one to establish clearly the viscosity range in which different techniques can operate with enough sensitivity for determining the interfacial shear viscosity. This review puts in perspective the most recent developments on the studies of the interfacial shear rheology of fluid/fluid interfaces, analyzing the strength and weakness of the different approaches.